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Chlorosulfonyl Isocyanate/ CSI

CAS NO. 1189-71-5
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Product Name Chlorosulfonyl Isocyanate (CSI)
(N-Carbonylsulfamyl Chloride / Sulfurisocyanatidic Chloride)
CAS NO. 1189-71-5
Formula & Weight CClNO₃S (MW: 141.53)
Chemical Structure CSI Structure
Technical Specifications
  • Appearance: Clear, colorless to pale yellow liquid

  • Assay (GC): ≥ 99.0%

  • Density (20°C): ~1.626 g/mL

  • Boiling Point: 106 - 108°C

  • Refractive Index: n20/D 1.447

  • Reactivity: Reacts violently with water (Hydrolyzes to Sulfamoyl Chloride).

Key Applications

A highly reactive electrophilic reagent for advanced synthesis:

  • Lithium Battery Electrolytes (LiFSI): Key precursor for synthesizing Bis(fluorosulfonyl)imide (FSI) and its lithium salt (LiFSI). CSI provides the sulfonyl-isocyanate skeleton essential for this next-gen electrolyte.

  • Pharmaceuticals (β-Lactams): Widely used in [2+2] cycloaddition reactions with alkenes to form β-lactam rings, a crucial step in synthesizing Cephalosporin antibiotics (e.g., Cefuroxime, Cefoxitin).

  • Agrochemicals & Sweeteners: Used to introduce sulfamoyl or carbamoyl groups into complex molecules, such as in the synthesis of Acesulfame K (sweetener) and specific herbicides.

  • Burgess Reagent Synthesis: Starting material for the preparation of the Burgess reagent (dehydrating agent).

Packaging & Storage Packaging: Stainless Steel Drum / Special Drum.

Storage: Strictly Moisture Free. Store in a cool (2-8°C recommended), dry, well-ventilated area under inert gas (Nitrogen/Argon).

Sourcing Precursors for LiFSI or Antibiotics?

Royalchem is an experienced supplier of highly reactive Chlorosulfonyl Isocyanate (CSI).        
We handle hazardous logistics safely and efficiently.

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